Some of the old treatments/chemicals can still have a good use. Calcium soap is one - WW2 and earlier used on Navy ships for rust prevention. My source is Lee Alox Bullet Lube, thinned ~20:1. This one not so much for wood. AI info:
“Sodium silicate” (often called
water glass) absolutely was used on wood in the late 1800s through mid-1900s—but it faded out for some very practical reasons.
What it did (and why people liked it)
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Back then, it was attractive because it was:
- Cheap and widely available
- Non-flammable
- Somewhat insect- and mold-resistant
- Added limited fire resistance (it forms a mineral-like layer)
Chemically, it soaks into wood pores and dries into a
glassy silica network—basically turning part of the surface into something closer to mineral than organic.
Why it fell out of favor for wood
Short version: it
kind of worked, but modern chemistry works far better.
1) Moisture sensitivity (biggest issue)
- Sodium silicate is water-soluble again after curing (especially with humidity exposure).
- That means:
- It can leach out over time
- Protection isn’t permanent outdoors
- Compared to modern sealers, it’s not a true waterproofing system
2) Surface problems
- Leaves a brittle, chalky/glassy film
- Can:
- Crack
- Flake
- Create a rough feel
- Not great for anything you want to look good or last structurally
3) Poor durability vs modern options
By the 1940s–1960s, better treatments showed up:
- Oil-based preservatives (e.g., creosote, pentachlorophenol)
- Pressure-treated lumber (CCA, later ACQ, etc.)
- Modern polymer sealers and epoxies
Those:
- Penetrate deeper
- Stay in place
- Handle weather cycles far better
4) Limited biological protection
- It’s mildly resistant to fungi/insects, but not nearly as effective as modern preservatives
- It doesn’t actively kill organisms the way later chemicals do
5) Alkalinity issues
- Highly alkaline → can:
- Damage finishes applied over it
- Cause long-term fiber degradation in some conditions
Why it is still used (just not much on wood)
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It didn’t disappear—it just found better applications.
Concrete (where it shines)
- Reacts with calcium hydroxide in concrete → forms calcium silicate hydrate (C-S-H)
- That:
- Hardens the surface
- Reduces dusting
- Improves durability
This is why it’s still common as a
concrete densifier/sealer
Other uses
- Fireproof coatings (industrial)
- Refractory cements
- Egg preservation (old-school trick)
- Adhesives and binders
Is it used on wood today at all?
Very niche:
- Some DIY fire-retardant treatments
- Occasional use in historic restoration
- Experimental “mineralization” treatments
But in real-world construction or woodworking?
It’s basically obsolete.
Bottom line (straight answer)
Sodium silicate fell out of use on wood because:
- It doesn’t stay stable with moisture
- It forms a brittle, mediocre protective layer
- It was outclassed by pressure treatments and modern sealers
It
survived in concrete because the chemistry there actually
improves the material permanently, instead of just coating it.